Transfer request: A self-assembled supramolecular charge-transfer complex of 1-(11-oxo-11-pyren-1-ylmethoxy)undecyl)pyridinium bromide (PYR) and ethane-1,2-diyl bis(3,5-dinitrobenzoate) (DNB) is shown to form vesicular aggregates in aqueous solution, in contrast to the tubular aggregates of pure PYR (see picture). A curvature-dependent mechanism for this change is proposed.
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Wang et al. (2008) studied this question.
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