7‐(Trifluormethyl)‐1λ4,3λ4,5λ4,‐trithia‐2,4,6,8,9‐pentaazabicyclo[3.3.1]nona‐1(9),2,3,5,7‐pentaen als Komplexligand

7‐(Trifluormethyl)‐1λ4,3λ4,5λ4,‐trithia‐2,4,6,8,9‐pentaazabicyclo[3.3.1]nona‐1(9),2,3,5,7‐pentaene as Ligand in Coordination Chemistry Many possibilities exist for the title compound CF3CN5S3 (3) (L) to coordinate to transition metal centers. From the reaction of 3 with [Ni(SO2)2](AsF6)2 and AgAsF6 in liquid SO2 [Ni‐(SO2)2L2(FAsF5)2) (11) and [AgL]AsF6 (13) or [AgL2]AsF6 (14), respectively, were isolated. As shown by X‐ray structure determination of 11 and 14, L coordinates as expected from MNDO calculations.