January 1, 1984Journal of the Chemical Society Chemical Communications

The X-ray crystal structure of trans-bis(sulphur dioxide)tetrakis(triphenylphosphineoxide)manganese(II) di-iodide, a compound which undergoes demi-reversible binding of sulphur dioxide: the first crystallographically characterised example of O-bonded sulphur dioxide in a transition metal complex

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Abstract

The X-ray crystal structure of the complex trans-[Mn(OPPh3)4(SO2)2]I2 shows it to contain O-bonded Sulphur dioxide groups; one of these can be lost to form Mn(OPPh3)4(SO2)I2, and the reaction is reversible.

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Cite This Study

Gott et al. (1984) studied this question.

synapsesocial.com/papers/6a919de9f4dc1bb5c47435d0 https://doi.org/10.1039/c39840001283

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