The organic–inorganic hybrid polymers poly(metal tetrathiooxalates), [MII(C2S4)]n, have so far only been available as insoluble and infusible powders, which restricts their applications. The first successful preparation—by a reactive self-assembly process—of ultrathin films of the polymers (see Figure) is described and their interesting electrical and optical properties are presented.
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Pyrasch et al. (2001) studied this question.
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