The reaction of (PNP)NiH, where PNP is ((t)Bu2PCH2SiMe2)2-N(-1), with CO2 occurs over a period of hours at 25 degrees C to form (POP)NiH(NCO), which involves transposition of the initial amide nitrogen and one oxygen of CO2.
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Laird et al. (2009) studied this question.
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