Multinuclear solid‐state‐NMR studies of hybrid organic‐inorganic materials

The powder of multinuclear solid‐state NMR for the investigation of the structural aspects of hybrid organic‐inorganic materials is demonstrated by the results presented here. It is shown that information about the organic groups can be obtained from 1H and 13C NMR and about the inorganic groups from 27Al and 29Si NMR; changes caused by the additional of a hardening component are revealed. Organic‐inorganic materials are of interest because they combine properties typical of inorganic compounds with the favorable mechanical properties of synthetic polymers.