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An effective Debye temperature Θ of carbides extracted from a tempered steel was determined through the Mössbauer effect. The f factor and Θ increase with tempering temperature, following a reduction of carbon content of the carbides and changes in the elastic properties. The phase transformation at Tc is followed by a discontinuity in the magnitude of the center shift and in ∂(δE/E)/∂T.
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Mathalone et al. (1970) studied this question.
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