syn-Tertiary homoallylic alcohols were obtained by the reaction of alpha-silylallenyltitanocenes generated by the reductive titanation of gamma-silylpropargylic carbonates with Cp(2)Ti[P(OEt)(3)](2) with ketones and following desilylation and partial hydrogenation. High diastereoselectivity was observed when aromatic and alpha,beta-unsaturated ketones were employed.
No takes yet. Share an insight, caveat, or question.
Yatsumonji et al. (2010) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: