We report on the successful growth of free-standing GaN films on (0001) sapphire substrates by RF-molecular beam epitaxy. The key to obtain unstrained GaN layers is employing self-organized GaN nano-columns which involve an air gap structure as a footing layer of overgrown GaN. The residual strain in overgrown GaN films is evaluated by measuring the lattice constant by X-ray diffraction. It is found that the c-axis length of overgrown GaN is estimated to be 5.1848 Å, which is close to the value of strain-free GaN even with a layer thickness of 2.7 µm. Overgrown GaN peeled arbitrarily from GaN nano-columns is observed due to the cleaving process.
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Kusakabe et al. (2001) studied this question.
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