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February 24, 2001The Journal of Organic Chemistry

α-Thiocyanation of Carbonyl and β-Dicarbonyl Compounds Using (Dichloroiodo)benzene−Lead(II) Thiocyanate

Om Prakash Harpreet Kaur Hitesh Batra Neena Rani Shiv P. Singh Robert M. Moriarty

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Abstract

The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.

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Prakash et al. (2001) studied this question.

synapsesocial.com/papers/6a922588af8726aa4b41d5ec https://doi.org/10.1021/jo001504i

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