A high-tech alternative to diamond and graphite: Supramolecular carbon allotropes are formed when single-walled carbon nanotubes are filled with C60 molecules. Similar “molecular peapods“ are also obtained by insertion of endohedral fullerenes and metallocenes into carbon nanotubes. Supramolecular nanotubes built up from porphyrins can also encapsulate C60 peas.
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Vostrowsky et al. (2004) studied this question.
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