Real-time and in situ monitoring of ferroelectric domains during periodic electric field poling of KTiOPO4

We demonstrate a photographic method to view the inversion of ferroelectric domains during the periodic electric field poling of KTiOPO4 by taking advantage of the electro-optic effect and a high speed charge coupled device (CCD) camera. The method is noninvasive and allows monitoring in situ and in real time. The high speed CCD camera opens up the possibility to observe the dynamics of the domains during poling and to probe the samples afterwards to evaluate the grating formed in the material. This monitoring method should be applicable to other ferroelectric crystals, as well.