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January 1, 2020Polymer Chemistry

Fundamental aspects of heterogeneous Ziegler–Natta olefin polymerization catalysis: an experimental and computational overview

Jugal Kumawat V.K. Gupta

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Abstract

Using an internal/external donor containing MgCl 2 -supported Ziegler–Natta catalyst is one of the important processes for polyolefin production.

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Kumawat et al. (2020) studied this question.

synapsesocial.com/papers/6a924f2632c5e70179c8046e https://doi.org/10.1039/d0py00753f

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin CompositesReview · 2015 · 821 citations
2A Preparation Method for Well‐Defined Crystallites of Mgcl2‐Supported Ziegler‐Natta Catalysts and their Observation by AFM and SEMOriginal Research · 2007 · 50 citations
3High-Resolution<sup>13</sup>C NMR Configurational Analysis of Polypropylene Made with MgCl<sub>2</sub>-Supported Ziegler−Natta Catalysts. 1. The “Model” System MgCl<sub>2</sub>/TiCl<sub>4</sub>−2,6-Dimethylpyridine/Al(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>Original Research · 1999 · 216 citations
4Structure of Donor Molecule 9,9-Bis(Methoxymethyl)-Fluorene in Ziegler-Natta Catalyst by Infrared Spectroscopy and Quantum Chemical CalculationOriginal Research · 2010 · 50 citations
5Electron spin resonance, titanium oxidation state, and ethylene polymerization studies of a model supported Ziegler-Natta catalyst. Spectroscopic detection of titanium tetrachlorideOriginal Research · 1987 · 50 citations

Full Assignment of the <sup>13</sup>C NMR Spectra of Regioregular Polypropylenes: Methyl and Methylene Region1997
Toward an Understanding of the Molecular Level Properties of Ziegler−Natta Catalyst Support with and without the Internal Electron Donor2010
Surface Investigation and Morphological Analysis of Structurally Disordered MgCl 2 and MgCl 2 /TiCl 4 Ziegler–Natta Catalysts2016
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