The reaction between (dimethylaminomethyl)ruthenocene with lithium tetrachloropalladate(II) in the presence of sodium acetate gave di-μ-chloro-bis[2-(dimethylaminomethyl)ruthenocenyl]dipalladium(II) (2). The σ-bonded structure of 2 has been confirmed by IR analysis and the reactions of 2 with triphenylphosphine, thallium(I) acetylacetonate, and lithium aluminum deuteride. The reactions of chloro [2-(dimethylaminomethyl)ruthenocenyl](triphenylphosphine)palladium(II) with carbon monoxide and 2 with methyl vinyl ketone, phenyl vinyl ketone, and styrene have been examined. 1,2-Disubstituted ruthenocene derivatives have been obtained in higher yields than those of the corresponding ferrocene derivatives.
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Kamiyama et al. (1979) studied this question.
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