Large Flexoelectriclike Response from the Spontaneously Polarized Surfaces in Ferroelectric Ceramics

Nonpoled ferroelectric ceramics are thought to be nonpolar because of randomly oriented grains and the formation of ferroelectric domains in the grains. Here, we discover the surfaces (∼several μm thick) of ferroelectric ceramics are spontaneously polarized. Because the orientations of ferroelectric polarization of the opposite surfaces are antiparallel, ferroelectric ceramics are nonpolar as a whole. However, the ceramics exhibit a strong flexoelectriclike electromechanical response from the piezoelectric response of the polarized surfaces if they are asymmetrically strained (such as bending). Our results reveal a major mechanism to resolve one important but largely unresolved issue: the experimentally measured flexoelectric effect is typically orders of magnitude larger than the theoretically predicted value in ferroelectrics.