Quantum Theory of Stimulated Raman Effect

A photon theory of the stimulated Raman effect is developed. A system of coupled equations for the amplitudes of scattered photons and molecular vibrations are derived. The molecular vibration coordinates are then eliminated using the random phase approximation. The equations which result assume the form of coupled equations for the first Stokes and anti-Stokes lights. The secular equation which characterizes the solution of these coupled equations is shown to be equivalent to that of Shen and Bloembergen. Using this secular equation, the condition for temporal growth of the scattered lights is obtained and is compared with that for the spatial growth, which was obtained previously by Shen and Bloembergen. It is shown that both types of growth (temporal and spatial) proceed with comparable rates if the damping of the molecular vibration is large. If its damping is small, however, the temporal growth prevails over the spatial growth. Typical line-shape of the anti-Stokes line is obtained in the case of small damping. The result shows a strong directionality, as is the case of large damping.