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The 13C chemical‐shift tensor orientations in the OCH2CH2O moieties of poly(ethylene oxide) (PEO) and poly(ethylene terephthalate) (PET) were determined by means of 1H13C separated‐local‐field NMR spectroscopy, and the literature values for the shift tensors in polyethylene (PE) and polyoxymethylene (POM) were improved. An angular resolution of ± 4° was attained on standard equipment with 90° pulse lengths exceeding 4 μs. Relatively high uniformity of the methylene tensor orientations, complying with local molecular symmetry, was found.
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Schmidt‐Rohr et al. (1993) studied this question.
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