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Bilayer electrodes derived from 3-methylthiophene and bithiophene, Pt/poly[tris(4-vinyl-4′-methyl-2,2′-bipyridine)ruthenium(II) perchlorate]/polythiophene, have been prepared. Their in situ reflection spectra upon electrochemical potential sweeps suggest the transient occurrence of polarons in the doped polythiophenes.
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Murao et al. (1986) studied this question.
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