This paper is a short review of our recent advances in Ziegler‐Natta catalyst system of the type (C5H5)2TiRCl/AlEtn Clm. These are, for instance, the electronic changes after complex formation, the parallel reactions of the alkyl and chain transfer between both the Ti centers of two complexes and the Ti center and an Al center of two complexes; furthermore, the alkyl, chain, and chlorine transfers between these complexes and dimer Al–alkyl, the time which the insertion step of one ethylene requires, and the mathematical calculation of the kinetics of the polyreaction.
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Fink et al. (1976) studied this question.
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