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Two new magnetic chain compounds, where the anionic [M(N3)2(HCOO)-]n chains with a 3-fold bridge of two end-on azido and one syn-syn formato ligands are isolated by the cations of [(CH3)2NH2]+, exhibit metamagnetism because of the strong intrachain ferromagnetic coupling versus the weak interchain antiferromagnetic coupling.
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Liu et al. (2006) studied this question.
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