The ligand L, which is ideally suited for octahedral coordination, forces this coordination geometry upon Pd11 in the diamagnetic complexes 1 (green) and 2 (blue) and also serves in 3 (orange-brown) as a tridentate ligand. In all three cases, however, the axial PdS bonds are significantly longer than the equatorial.
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Wieghardt et al. (1986) studied this question.
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