Novel [LPdCl] 3 trimers (L = chiral secondary benzylamine) were synthesized via direct cyclopalladation. The structures of trimeric palladacycles were confirmed by means of X-ray analysis. The secondary interactions stabilizing trimeric molecules were investigated. An equilibrium between dimeric and trimeric palladacycle species was found in solution by means of dynamic NMR- spectroscopy and ESI mass spectrometry study.
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Vatsadze et al. (2009) studied this question.
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