p -type doping in organic light emitting diodes based on fluorinated C60

We report on hybrid organic light emitting diodes based on spin coated PVK (poly(vinylcarbazole))/poly-TPD (poly(triphenyldiamine)) formulation electron blocking and conjugated peptide emitter layers while the hole blocking, BCP (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline), layer is vacuum sublimed. The device structure is realized through the use of fluorinated C60 as a p-dopant in a cross-linked hole transporting formulation. The lowering of the turn-on voltage is demonstrated using a conjugated peptide as the emitter layer. We suggest that fluorinated C60s could play a major role as tunable dopants in organic electronics.