orbital in contributing to the metallic conductance through crossing the system Fermi level. The binding between PANI layers is 61.68 meV per atom, indicating that the interlayer interaction within PANI stacks is mostly van der Waals attraction. This striking semiconductor-to-metal transition realized in one homogeneous 2D nanomaterial only through thickness control should open up new opportunities for the design of seamless electronic contacts and constitute the ultimate functional unit for future nano-electronic devices.
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Li et al. (2017) studied this question.
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