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Cyclophellitol [1l-(1,2,4,6/3,5)-1,2-anhydro-6-(hydroxymethyl)-cyclohexane-1,2,3,4,5-pentol], a novel β-glucosidase inhibitor, has been synthesized from d-glucose via a branched-chain 6-deoxyhex-5-enopyranoside.
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Sato et al. (1994) studied this question.
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