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August 29, 2026Journal of Geophysical Research Solid EarthOpen Access

Stability of Water‐Bearing Aluminous Silica Phases in Subducted Oceanic Crust: Implications for Water Transport to the Core‐Mantle Boundary

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Authors

YYYao YaoLLLu LiuZYZiqiang Yang

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Overview

Experimental study reveals stable hydrous aluminous silica and iron oxyhydroxide in subducted oceanic crust, indicating water transport mechanisms extending to the core-mantle boundary.

Key Points

  • Investigate water storage capacity, phase transitions, and mineral stability in hydrous basaltic systems representing subducted oceanic crust under deep lower mantle conditions.
  • Conducted high-pressure and high-temperature experiments in the MgO-Al2O3-Fe2O3-SiO2-H2O system across pressures of 94–134 GPa and temperatures of 2,100–2,500 K.
  • Evaluated phase boundaries by comparing water-bearing basaltic compositions containing high alumina against alumina-poor hydrous silica systems under matching conditions.
  • Stabilized NiAs-type silica in water-bearing basaltic compositions along normal lower-mantle geotherms, confirming that high alumina content coupled with water is required to maintain this structure.
  • Observed CaCl2-type silica instead in alumina-poor hydrous systems under the same pressure-temperature conditions, delineating a distinct phase boundary between the two structural types.
  • Documented the stable coexistence of aluminous silica and pyrite-type FeOOH under extreme conditions corresponding to mantle depths greater than 2,300 km.

Cite This Study

Yao et al. (2026) studied this question.

synapsesocial.com/papers/6a92be7b8e5d7d1fc0c12303https://doi.org/10.1029/2026jb034479
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