We report on the design and characterization of methylmethacrylate copolymers with nonlinear optical 4-alkoxy-4′-alkylsulfone stilbene sidechains, which are transparent down to 410 nm. A fairly stable, polar orientation has been obtained by means of electric field poling, resulting in a reasonably high nonlinearity (d33≤9 pm/V).
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Rikken et al. (1991) studied this question.
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