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September 1, 1969Journal of the American Oil Chemists Society

The mechanism of the aqueous perchloric acid isomerization of oleic acid to γ‐stearolactone

I. S. Shepherd John S. Showell

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Abstract

The migration of the double bond in the reaction of oleic acid with aqueous 67% deuteroperchloric acid occurs by the reversible intermolecular esterification of carboxylic acid by olefin; when a double bond reaches the Δ4,5 position and intramolecular carboxylic acid‐olefin, esterification occurs to yield γ‐stearolactone.

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Shepherd et al. (1969) studied this question.

synapsesocial.com/papers/6a92d302057b0bba391f5fdb https://doi.org/10.1007/bf02544372

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