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A clean break: The novel catalytic conversion of hexafluoropropene into (3,3,3-trifluoropropyl)silanes by CF activation has been developed (see scheme). The reactions are catalyzed by the rhodium complex [Rh{(Z)-CFCF(CF3)}(PEt3)3], proceed at room temperature, and are highly selective.
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Braun et al. (2007) studied this question.
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