The lifetime and predissociation probabilities of various rotational levels of the A2∑+ state of OD were measured. A strong predissociation at N′ = 35 was observed. This predissociation could be explained by the level crossing of the A2∑+ state with the repulsive 4∑− state which are mixed by a weak spin–orbit interaction.
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Wilcox et al. (1975) studied this question.
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