In the electroreduction of carbon dioxide, catalytic activities of the tetrasulfonated metal phthalocyanines(MeTSP) homogeneously dissolved in the Clark–Lubs buffer solutions were investigated by the measurements of current- and capacitance-potential curves. It was found that CoTSP and NiTSP were active but not CuTSP and FeTSP.
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Hiratsuka et al. (1977) studied this question.
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