A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (L″ = N(Ar*)(SiPh 3 ); Ar* = C 6 H 2 {C(H)Ph 2 } 2 Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [L″Co(IPriMe)] (IPriMe =:C{N(Pr i )C(Me)} 2 ), which has a near-linear cobalt coordination geometry.
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Hicks et al. (2015) studied this question.
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