1H and 31P NMR studies show that in aqueous solution the anticancer agent titanocene dichloride (Cp2TiCl2) binds selectively to N,N′-ethylenebis(o-hydroxyphenylglycine) (H4ehpg) at neutral pH, but preferentially to adenosine triphosphate (ATP) at pH* values below 5.1; intermolecular TiIV transfer from [TiIV(ehpg)(H2O)] to ATP occurs at acidic pH values.
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Guo et al. (2000) studied this question.
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