Answers are grounded in this paper and cite their sources.
The left-handed isomer of the helical complex [LZn(3)La(OAc)(3)] was spontaneously enriched from 50 : 50 to 87 : 13 when the quasiracemate crystals were dissolved. The invertible helicity of [LZn(3)La(OAc)(3)] (global chirality) helps the quasiracemate formation and the fixed point chirality of the R,R-cyclohexanediamine moiety (local chirality) effectively controls the global chirality in solution.
No takes yet. Share an insight, caveat, or question.
Akine et al. (2011) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: