January 1, 1984Bulletin des Sociétés Chimiques BelgesOpen Access

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

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Authors

ADAlbert DemonceauUniversity of Liège ANAlfred F. NoelsEuropean Union AHA. J. HubertEuropean Union

Abstract

Rhodium(II) carboxylates associated with bulky ligands catalyse the insertion of carbalkoxycarbenes (generated from diszoesters) into C‐H bonds of normal and branched alkanes with selectivities differing substantially from those associated with non‐bulky carboxylates.

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Demonceau et al. (1984) studied this question.

synapsesocial.com/papers/6a9376ff8b36a15ffccd74b3 https://doi.org/10.1002/bscb.19840931103

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Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Abstract

Discussion

Cite This Study

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Abstract

Discussion

Cite This Study

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