Stabilized by GaCl4− ions, the π-arene–mercury complex [Hg(η2-C6H5CH3)2(GaCl4)2] could be characterized by 199Hg and 13C CPMAS NMR spectroscopy and X-ray crystallography (see picture). This unusually stable mercury–toluene complex catalyzes hydrogen/deuterium exchange between toluene and [D6]benzene.
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Borovik et al. (2000) studied this question.
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