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April 15, 2003Organic Letters

Enantio- and Diastereoselective Synthesis of Cyclic β-Hydroxy Allylsilanes via Sequential Aldehyde γ-Silylallylboration and Ring-Closing Metathesis Reactions

Jung‐Nyoung Heo Glenn C. Micalizio William Roush

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Abstract

[reaction: see text] Highly enantioenriched cyclic allylsilanes are prepared via stereoselective gamma-silylallylboration reactions of beta- or gamma-unsaturated aldehydes followed by ring-closing metathesis.

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Heo et al. (2003) studied this question.

synapsesocial.com/papers/6a937742ab3ace8d8eff057d https://doi.org/10.1021/ol034347t

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