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Experimental study demonstrates enantioselective three-component carboamination of dienes via rhodium catalysis, suggesting a direct route to functionalized chiral allylic amines.
Reported herein is the rhodium-catalyzed enantioselective three-component coupling of arene, diene, and dioxazolone that occurs via C–H activation en route to allyl intermediate. This carboamination reaction affords chiral allylic amines in 1,2-selectivity, E -selectivity, and enantioselectivity, with electrophilic amination of the π-allyl species being both regio- and enantio-determining.
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Mi et al. (2021) studied this question.
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