A cancerostatic cyclopeptide from a marine organism, which contains both thiazole as well as dihydrooxazole rings, was the first of its kind to be synthesized. A key step in the synthesis is the condensation of the thiazoles 1 and 2 (generated from (S)-isoleucine and (S)-alanine, respectively).
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Schmidt et al. (1985) studied this question.
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