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Ozonolysis of ethyl vinyl ether ( 7a ) in the presence of the O -methylated oxime of cyclohexanone ( 8 ) afforded N -methoxy-1,2-dioxa-4-azaspiro[4.5]decane ( 9a ), and ozonolyses of the O -methylated dioximes of 1,4- and 1,5-dicarbonyl compounds ( 10a − e ) afforded N -methoxylated bicyclic 1,2,4-dioxazolidines ( 12a − e ).
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Griesbaum et al. (1998) studied this question.
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