A new cat. for chiral phosphines: A highly enantioselective allylic phosphination reaction is realized using the Pd–Josiphos(L) catalyst system. This CP bond forming reaction provides a new access to chiral phosphines (see scheme) that may be further functionalized. Cy=cyclohexyl, dba=trans,trans-dibenzylideneacetone.
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Butti et al. (2008) studied this question.
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