Poly[(2-cinnamoylethyl methacrylate)- random -(2-octanoylethyl methacrylate)]- block -poly(acrylic acid) [P(CEMA- r -OEMA)- b -PAA] forms micelles in water with P(CEMA- r -OEMA) as the core and PAA as the shell. POEMA is incorporated into the micellar cores. After PCEMA cross-linking, POEMA is extracted to produce porous water-soluble P(CEMA- r -OEMA)- b -PAA nanospheres. The porous nanospheres sorb a significantly higher amount of perylene from water/acetone and water/acetone/DMSO mixtures than the nonporous P(CEMA- r -OEMA)- b -PAA nanospheres.
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Henselwood et al. (1998) studied this question.
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