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Complex 2 is formed by two discrete ions which originate during hydrogenolysis of 1 according to Equation (a). The cation is dinuclear with three bridging hydrido ligands. The mixed‐valent anion of 2 is also dinuclear and contains two bridging nitrido moieties, which cannot be the product of the hydrogenolysis of NSi bonds since silanes are not formed in the reaction. equation image
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Berno et al. (1995) studied this question.
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