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An instrument to measure the rotational and vibrational energies of heterogeneous reaction products has been constructed. Reactant atoms pass through a membrane made of the material being studied. After recombination and desorption occurs, the product gas is analyzed via either electron beam or laser-induced fluorescence. Surface composition is monitored by soft x-ray appearance potential spectroscopy. Results for nitrogen molecule desorption from clean, polycrystalline iron are presented in order to illustrate the capabilities of the apparatus.
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Thorman et al. (1981) studied this question.
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