In copolymerization, Arlman's equation was modified to wherektabis an apparent cross‐termination rate constant depending on a ratiof1= [A]/[B], andKz(x= 1, 2, 3, 4) is the ratio of each cross‐termination rate constant depending on the penultimate unit to the geometric meanK̄tabof two termination rate constants in homopolymerizations. The calculated values of (K1+K2/r1r2) by using this equation were related toK1+K2/r1r2= 18/r1r2.
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Katsukiyo Ito (1970) studied this question.
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