Surface plasmon polariton mediated energy transfer in organic photovoltaic devices

The performance of a phthalocyanine-based photovoltaic is boosted in the absorption gap between the phthalocyanine Q and Soret bands. Light absorption is decoupled from exciton diffusion using a light absorbing “antenna” layer external to the conventional charge generating layers. Radiation absorbed by the antenna is transferred into the charge generating layers via surface plasmon polaritons in an interfacial thin silver contact. The peak efficiency of energy transfer is measured to be at least (51±10)%.