Single Nanoparticle Plasmonic Devices by the “Grafting to” Method

Hierarchically organized single-nanoparticle structures synthesized in this work consisted of a 200 nm silica core and a pH-responsive poly(2-vinylpyridine) shell decorated with 15 nm gold nanoparticles. pH changes in the range of 3-6 back and forth results in a swelling-shrinking polymer brush shell and, thus, in the tuning distance between noble nanoparticles. A change in the interparticle distance is accompanied by a very pronounced shift in the maximum wavelength of the surface plasmon absorption peak. The dispersion of the resulting composite nanoparticles reversibly changed color from red to purple-blue as the pH changed from 2.5 to 6. Such hierarchically assembled nanostructures can be used as free-standing single-particle sensors in various miniaturized analytical systems.