Only under very restrictive conditions can the non‐equilibrium thermodynamic theories of dissipative processes in continuous media be applied to a description of dyeing systems. A primary restriction results from the complex physico‐chemical nature of fibrous polymers. Under certain conditions, the assumption that a textile substrate may be regarded as a water‐swollen, isotropic gel is possible, and circumvents this restriction.
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McGregor et al. (1966) studied this question.
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