A new model for the description of incoherent peaks observed in energy‐dispersive x‐ray fluorescence spectra is proposed. The model was derived after a systematic study of peak shapes based on Monte Carlo simulations. The model consists of a Gaussian modified by two exponential tail functions. The model is implemented in a non‐linear least‐squares fitting procedure and tested on spectra measured with a 109 Cd excitation XRF setup using an HPGe detector.
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Gysel et al. (2003) studied this question.
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