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Efficient and practical: An aluminum-based catalyst system for the asymmetric Meerwein–Schmidt–Ponndorf–Verley reduction of aromatic ketones is reported. By using iPrOH as the achiral hydride source and BINOL-type chiral ligands (see scheme), chiral secondary aromatic alcohols (up to 83 % ee) can be obtained in good yields.
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Campbell et al. (2002) studied this question.
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